Product ID:FREON TP SOLVENT AZEOTROPE AND BLENDS, (SUP
MSDS Date:08/16/1992
FSC:6850
NIIN:00-112-7330
MSDS Number: BQGLQ

E I DU PONT DE NEMOURS & CO INC

1251 BRANDYWINE BLDG
WILMINGTON, DE 19898
US

Emergency Phone: 800-441-3637;800-424-9300(CHEMTREC)

Info Phone: 302-773-5676

Cage: B0589

E I DU PONT DE NEMOURS & CO

BRUSSEL, DE 19898 BE

Telephone: 32-(0)15-401.505

Cage: B0589

ETHANE, 1,1,1-TRICHLORO-2,2,2-TRIFLUORO-;

CAS: 354-58-5

RTECS: KJ3975000

Fraction By Weight: 64.7%

(RAT)

CAS: 67-63-0

RTECS: NT8050000

Fraction By Weight: 35%

OSHA PEL 400 PPM;500 PPM STEL

ACGIH TLV: 400 PPM;500 PPM STEL

METHANE, NITRO-

CAS: 75-52-5

RTECS: PA9800000

Fraction By Weight: 0.30%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

HAZ THAN ALLOWING IT TO PROGRESS THRU THE

RTECS: 9999999ZZ

ELICITING CARDIAC DYSRYTHMIAS, CATECHOLAMINE DRUGS,

RTECS: 9999999ZZ

AS A LAST RESORT IN LIFE THREATENING EMERGENCIES.

RTECS: 9999999ZZ

IS POORLY ABSORBED THROUGH THE SKIN. EYE

RTECS: 9999999ZZ

MATLS HAVE PRODUCED SENSIT OF THE MYOCARDIUM TO

RTECS: 9999999ZZ

IN HUMANS. ADRENOMIMETICS (E.G. EPINEPHRINE) MAY BE

RTECS: 9999999ZZ

IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO

RTECS: 9999999ZZ

ALCOHOL PORTION IS MISCIBLE WITH

RTECS: 9999999ZZ

NONE TO BOIL. FREON T-P 35 REDUCES TO 90%

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:VAP IS HVR/AIR & MAY CAUSE
SUFFOCATION BY REDUCING OXYGEN AVAIL FOR BRTHG. BRTHG HIGH CONC OF
THESE PRODS CAN CAUSE LT HEAD, GIDDINESS, SHORTNESS OF BREATH,
IRRIT OF THE UPPER RESP PASSAGES, & M AY LEAD TO NARCOSIS, CARDIAC
IRREGULARITIES, UNCON/DEATH. NOTE:IN SCANNING TESTS W/EXPERIMENTAL
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: ANIMALS, EXPOSED TO FREON 113 AT
APPROX 5,000 PPM (V/V) AND ABOVE, FOLLOWED BY A LARGE INTRAVENOUS
EPINEPHRINE CHALLENGE, HAS INDUCED SERIOUS CARDIAC IRREGULARITIES.
SKIN: NOT A CORROSIVE/IR RIT AFTER SINGLE CNTCT; HOWEVER, RPTD LIQ
CNTCT CAN CAUSE DEFATTING OF THE SKIN RESULTING IN IRRIT. THIS MATL
(ING 7)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:REMOVE TO FRESH AIR, CALL MD. IF NOT BRTHG, GIVE ARTF
RESP, PREFERABLY MOUTH-TO-MOUTH. IF BRTHG IS DIFFICULT, GIVE
OXYGEN. DO NOT GIVE EPINEPHRINE/SIMILAR DRUGS. EYE:IMMED FLUSH
W/PLENTY OF WATE R FOR @ LST 15 MIN. CALL MD. SKIN:FLUSHW/WATER.
GET MED ATTN IF IRRIT IS PRESENT. INGEST:NO SPECIFIC INTERVENTION
IS INDICATED AS THE MATL IS NOT LIKELY TO BE HAZ BY INGEST. DO NOT
INDUCE (SUPP DATA)

Flash Point Method:TOC
Flash Point:ING 12
Lower Limits:NONFLAMMABLE
Upper Limits:NONFLAMMABLE
Extinguishing Media:NON FLAMMABLE. USE EXTINGUISHING MEDIA SUITABLE FOR
SURROUNDING FIRE .
Fire Fighting Procedures:ADDTN OF EXCESS WATER WILL EXTRACT ISOPROPYL
ALCOHOL & MAY FORM A FLAMM SUPERNATANT LAYER. NIOSH/MSHA APPRVD
PRESS DEMAND SCBA & FULL PROT EQUIP IS (SUPP DATA)
Unusual Fire/Explosion Hazard:DRUMS MAY RUPTURE UNDER FIRE CONDITIONS.
DECOMPOSITION MAY OCCUR. THERMAL DECOMP PRODS MAY INCLUDE
CHLORIDES, FLUORIDES & PHOSGENE .

Spill Release Procedures:VENTILATE AREA. DO NOT FLUSH INTO SEWERS. DIKE
SPILL. COLLECT ON ABSORBENT MATERIAL & TRANSFER TO STEEL DRUMS FOR
RECOVERY OR DISPOSAL. COMPLY W/FEDERAL, STATE, AND LOCAL
REGULATIONS ON REPORTING RELE ASES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:SHIPPING CONTAINERS: DRUM, TANK
TRUCKS, TANK CARS. CLEAN, DRY AREA. DO NOT HEAT ABOVE 125 F.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATIOIN MAY CAUSE THE FORMATION OF CHLORIDES, FLUORIDES,
AND/OR PHOSGENE (F P N).

Respiratory Protection:UNDER NORMAL MANUFACTURING CONDITIONS NO
RESPIRATORY PROTECTION IS REQUIRED WHEN USING THIS PRODUCT.
NIOSH/MSHA APPROVED SCBA IS REQUIRED IF A LARGE SPILL OCCURS.
Ventilation:NORMAL VENT FOR STD MFG PROC IS GENERALLY ADEQ. LOC EXHST
SHLD BE USED WHEN LRG AMTS ARE RELEASED. LOW PLACES:MECH VENT.
Protective Gloves:BUTYL GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR TRADE NAME/PART NO:FC-99, FREON T-P 35. FIRE FIGHT PROC: REQUIRED
IF DRUMS RUPTURE & CONTENTS ARE SPILLED UNDER FIRE CONDITIONS.
DECOMP PROD: HYDROCHLORIC & HYDROFLUORIC ACIDS AND POSSIBLE CARBONY
L HALIDES. PHOSGENE . FIRST AID PROC: VOMIT AS THE HAZ OF ASPIR THE
MATL INTO THE LUNGS IS A GREATER (ING 4)

Boiling Pt:B.P. Text:120F,49C
Vapor Pres:151 @ 77F
Vapor Density:1.15
pH:NEUT
Solubility in Water:ING 11
Appearance and Odor:CLEAR, COLORLESS LIQUID, SLIGHT SOLVENT ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS-POWDERED ALUMINUM, ZINC, BARIUM.
Stability Condition to Avoid:AVOID OPEN FLAMES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:THE COMPONENTS OF THESE BLENDS CAN BE
DECOMPOSED BY HIGH TEMPS (OPEN FLAMES, GLOWING METAL SURF,ETC.)
FORMING(SUPP DATA)

Waste Disposal Methods:COMPLY WITH FEDERAL, STATE AND LOCAL
REGULATIONS. REMOVE TO A PERMITTED WASTE DISPOSAL FACILITY. EPA
HAZARDOUS WASTE NOS. F001 AND F002 MAY APPLY TO WASTE MATERIALS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.